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                                  | 论文编号: | 1222140120140024 |  
                                  | 第一作者所在部门: | 609组 |  
                                  | 中文论文题目: | Enhanced thermochemical CO2 splitting over Mg-and Ca-doped ceria/zirconia solid solutions |  
                                  | 英文论文题目: | Enhanced thermochemical CO2 splitting over Mg-and Ca-doped ceria/zirconia solid solutions |  
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                                  | 刊物名称: | RSC Advances |  
                                  | 年: | 2014 |  
                                  | 卷: |  |  
                                  | 期: | 4 |  
                                  | 页: | 5583-5590 |  
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                                  | 影响因子: | 3.708 |  
                                  | 摘要: | Thermochemical CO2 splitting was carried out over ceria/zirconia solid solutions prepared viaa P123-added hydrothermal method in the temperature range of 1100–1400 C. XRD, Raman and TPR characterization indicated that the introduction of Mg and Ca into ceria/zirconia could produce lattice defects in the fluorite lattice, and then strongly modify the mobility of oxygen as well as the thermal stability of the samples. As compared to Mg-doped samples, faster reaction rates and higher CO2 splitting |  
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