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| 论文编号: |
1222140120150287 |
| 第一作者所在部门: |
311组 |
| 中文论文题目: |
Glucosamine condensation catalyzed by 1-ethyl-3-methylimidazolium acetate:mechanistic insight from NMR spectroscopy
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| 英文论文题目: |
Glucosamine condensation catalyzed by 1-ethyl-3-methylimidazolium acetate:mechanistic insight from NMR spectroscopy
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| 论文题目英文: |
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| 作者: |
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| 论文出处: |
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| 刊物名称: |
Phys.Chem.Chem.Phys
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| 年: |
2015
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| 卷: |
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| 期: |
17 |
| 页: |
23173-23182 |
| 联系作者: |
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| 收录类别: |
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| 影响因子: |
4.493
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| 摘要: |
The basic ionic liquid 1-ethyl-3-methylimidazolium acetate ([C2C1Im][OAc]) could efficiently catalyze the conversion of 2-amino-2-deoxy-D-glucose (GlcNH2) into deoxyfructosazine (DOF) and fructosazine (FZ).Mechanistic investigation by NMR studies disclosed that [C2C1Im][OAc], exhibiting strong hydrogen bonding basicity, could coordinate with the hydroxyl and amino groups of GlcNH2 via the promotion of hydrogen bonding in bifunctional activation of substrates and further catalyzing product |
| 英文摘要: |
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| 备注: |
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