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| 论文编号: |
122214O120120143 |
| 第一作者所在部门: |
704组 |
| 中文论文题目: |
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| 英文论文题目: |
Preparation and Properties of Octadecahedral α-Fe2O3 Nanoparticles Enclosed by {104} and {112} Facets
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| 论文题目英文: |
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| 作者: |
刘忠
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| 论文出处: |
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| 刊物名称: |
European Journal of Inorganic Chemistry
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| 年: |
2012
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| 卷: |
2012 |
| 期: |
25 |
| 页: |
4076-4081 |
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| 收录类别: |
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| 影响因子: |
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| 摘要: |
Octadecahedral α-Fe2O3 nanoparticles were hydrothermally synthesized in the presence of formamide. These octadecahedral α-Fe2O3 nanoparticles have a threefold axis and are enclosed by twelve dominant {112} facets and six {104} facets.In comparison with the {104} facets, the sterically less hindered {112} facets induced the selective adsorption of formamide more easily, which resulted in the gradual increase in the amount of {112} facets by decreasing the amount of{104} facets with increasing formamide. The coercivity (Hc)
of these octadecahedral particles increased successively as the aspect ratio (c/a) increased. The sensing capability of these particles toward H2O2 was investigated, and the response currents of the particles dominated by {112} facets showed a linear relationship with a concentration of H2O2 in
the range from 40 μM to 6.66 mM in different stages. |
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